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215 questions
Chemistry/Paper 1/Experimental Techniques and Chemical Analysis
CAIEO-Level5070-o · Paper 1

Experimental Techniques and Chemical Analysis

215 questions· page 1 of 22

Q382025 May/Jun·P111MMedium-Easy

A titration is completed.

25.0 cm325.0\text{ cm}^3 of aqueous sodium hydroxide is added to a conical flask.

A few drops of methyl orange indicator are added.

Dilute hydrochloric acid is added slowly to the mixture until the colour changes.

Which row is correct?

Options

apparatus used to add alkaliapparatus used to add acidcolour change of indicator
Avolumetric pipetteburettered to orange
Bmeasuring cylinderburettered to orange
Cvolumetric pipetteburetteyellow to orange
Dvolumetric pipettemeasuring cylinderyellow to orange
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Q392025 May/Jun·P111MMedium-Easy

An impure sample of compound X has a melting point of 120C120\,^\circ\text{C}.

X is purified and its melting point is measured again.

Which row is correct?

Options

method of purifying Xmelting point of pure X / C^\circ\text{C}
Acrystallisation125
Bcrystallisation115
Cdistillation125
Ddistillation115
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Q402025 May/Jun·P111MMedium-Easy

Samples of two compounds, P and Q, are tested. The result of each test is shown.

testPQ
add dilute hydrochloric acidgas given off that turns limewater milkyno observable change
acidify with dilute nitric acid then add aqueous barium nitrateno precipitate formswhite precipitate
add aqueous sodium hydroxideno observable changegreen precipitate, soluble in excess
add aqueous ammoniano observable changegreen precipitate, insoluble in excess
flame testlilac flamenot tested

Which row shows the identities of the ions present in P and Q?

Options

PQ
AK+\text{K}^+ and SO42\text{SO}_4^{2-}Cr3+\text{Cr}^{3+} and CO32\text{CO}_3^{2-}
BK+\text{K}^+ and CO32\text{CO}_3^{2-}Fe2+\text{Fe}^{2+} and SO42\text{SO}_4^{2-}
CK+\text{K}^+ and CO32\text{CO}_3^{2-}Cr3+\text{Cr}^{3+} and SO42\text{SO}_4^{2-}
DLi+\text{Li}^+ and CO32\text{CO}_3^{2-}Cr3+\text{Cr}^{3+} and SO42\text{SO}_4^{2-}
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Q372025 May/Jun·P121MEasy

Four samples are analysed using paper chromatography.

P, Q and R are pure substances.

M is a mixture of different substances.

Which substances does mixture M contain?

Options

A   P, Q and R
B   P, Q and another substance
C   P and Q only
D   P and R only

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Q382025 May/Jun·P121MEasy

A student is making a sample of aqueous copper(II) sulfate. The student adds an excess of copper(II) oxide powder to warm sulfuric acid and stirs the mixture.

Which apparatus is used to separate aqueous copper(II) sulfate from the excess copper(II) oxide?

Options

A   burette
B   distillation apparatus
C   filter funnel and paper
D   measuring cylinder

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Q402025 May/Jun·P121MMedium-Easy

A sample of a white powder, X, is dissolved in water.

Tests are done on separate portions of this solution and the observations are shown in the table.

testobservation
add aqueous sodium hydroxide a drop at a time until in excesswhite precipitate forms, soluble in excess, giving a colourless solution
acidify with dilute nitric acid then add aqueous silver nitratewhite precipitate forms
acidify with dilute nitric acid then add aqueous barium nitratethe solution remains colourless

What is X?

Options

A   aluminium chloride
B   aluminium sulfate
C   calcium chloride
D   calcium sulfate

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Q372025 Oct/Nov·P111MEasy

Which diagram shows a measuring cylinder?

Options

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Q382025 Oct/Nov·P111MEasy

A chromatogram of mixture X and pure substances P, Q, R and S is shown.

Which statement is correct?

Options

A   R is completely insoluble in the solvent used.
B   The RfR_f value of Q is greater than the RfR_f value of S.
C   X is a mixture of Q, R and S.
D   The paper is placed in the solvent with the solvent above the baseline.

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Q392025 Oct/Nov·P111MMedium-Easy

Sulfur dioxide is a gas that is prepared by heating sodium sulfite with hydrochloric acid. It is an acidic gas. Sulfur dioxide is more dense than air.

Which set of apparatus is suitable for preparing and collecting a dry sample of sulfur dioxide?

Options

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Q402025 Oct/Nov·P111MEasy

A colourless solution of compound W is tested separately with a few drops of aqueous sodium hydroxide and a few drops of aqueous ammonia.

No precipitate is observed in either of the tests.

What is the cation in W?

Options

A   Al3+\text{Al}^{3+}
B   Ca2+\text{Ca}^{2+}
C   Cu2+\text{Cu}^{2+}
D   NH4+\text{NH}_4^+

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