9701/21

Chemistry 9701/21October/November 2019

Cambridge AS Level · AS Level Structured Questions · worked solutions for every part, with the mark scheme

4
questions
60
marks
75
minutes

Topics Chemical Bonding · Hydrocarbons · Chemical Energetics · Analytical Techniques · Electrochemistry · Group 17 · +7 more

Q1ElectrochemistryGroup 17Chemical BondingHydrocarbonsFree sample
(a)

Chlorine can be prepared using the following reaction.

MnO2(s)+4HCl(aq)MnCl2(aq)+2H2O(l)+Cl2(g)\text{MnO}_2(\text{s}) + 4\text{HCl}(\text{aq}) \rightarrow \text{MnCl}_2(\text{aq}) + 2\text{H}_2\text{O}(\text{l}) + \text{Cl}_2(\text{g})
(i)

Explain why MnO2(s)\text{MnO}_2(\text{s}) is described as an oxidising agent in this reaction.

Refer to oxidation numbers in your answer.

1M
(ii)

State what you would observe during this reaction.

1M
(b)

The halogens chlorine, bromine and iodine are all volatile elements.

State and explain the trend in volatility down Group 17.

3M
(c)

Chlorine undergoes disproportionation during many chemical reactions.

(i)

Write an equation for the reaction of chlorine with cold aqueous sodium hydroxide, NaOH\text{NaOH}.

Explain why it is a disproportionation reaction.

equation

explanation

2M
(ii)

One of the products of the reaction of chlorine with hot aqueous sodium hydroxide differs from those in (c)(i).

Identify the compound that is formed in this reaction that is different from that formed in the reaction in (c)(i).

1M
(d)

State and explain the use of chlorine in water purification.

2M
(e)

Under certain conditions, chlorine undergoes a free-radical substitution reaction with ethane.

(i)

State the conditions required to initiate this reaction.

1M
(ii)

Write the overall equation for this free-radical substitution reaction.

1M

The rest of this paper

3 more questions
  • Q2Chemical Periodicity · States of Matter · Chemical Bonding · Chemical Energetics13M
  • Q3Hydrocarbons · Analytical Techniques · Chemical Energetics · Atoms, Molecules and Stoichiometry13M
  • Q4Introduction to Organic Chemistry · Hydroxy Compounds · Chemical Bonding · Carboxylic Acids and Derivatives · Carbonyl Compounds · Analytical Techniques22M
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