9701/22

Chemistry 9701/22October/November 2015

Cambridge AS Level · AS Level Structured Questions · worked solutions for every part, with the mark scheme

4
questions
60
marks
75
minutes

Topics Atomic Structure · Chemical Bonding · Chemical Energetics · Atoms, Molecules and Stoichiometry · Chemical Periodicity · Nitrogen and Sulfur · +5 more

Q1Atomic StructureChemical BondingFree sample

Answer all the questions in the spaces provided.

(a)

Fill the gaps in the table for each of the given particles.

name of isotopetype of particlechargesymbolelectron configuration
carbon-131s22s22p21s^22s^22p^2
1-11737Cl^{37}_{17}\text{Cl}^-
sulfur-34atom00
iron-54cation1s22s22p63s23p63d61s^22s^22p^63s^23p^63d^6
5M
(b)

One of the factors that determines the type of bonding present between the particles of a substance is the relative electronegativities of the bonded particles.

(i)

Explain the meaning of the term electronegativity.

2M
(ii)

Name and describe the type of bonding you would expect to find between particles with equal electronegativities.

2M
(iii)

Name and describe the type of bonding you would expect to find between particles with very different electronegativities.

2M
(c)

The boiling points of some molecules with equal numbers of electrons are given.

substancefluorineargonhydrogen chloridemethanol
formulaF2\text{F}_2Ar\text{Ar}HCl\text{HCl}CH3OH\text{CH}_3\text{OH}
boiling point / K8587188338
(i)

Explain why the boiling points of fluorine and argon are so similar.

2M
(ii)

Explain why the boiling point of hydrogen chloride is higher than that of fluorine.

2M
(iii)

Explain why methanol has the highest boiling point of all these molecules.

2M

The rest of this paper

3 more questions
  • Q2Chemical Energetics · Atoms, Molecules and Stoichiometry7M
  • Q3Chemical Periodicity · Nitrogen and Sulfur14M
  • Q4Halogen Compounds · Introduction to Organic Chemistry · Nitrogen Compounds · Carboxylic Acids and Derivatives · Hydrocarbons22M
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