9701/22

Chemistry 9701/22May/June 2013

Cambridge AS Level · AS Level Structured Questions · worked solutions for every part, with the mark scheme

5
questions
60
marks
75
minutes

Topics Hydroxy Compounds · Atoms, Molecules and Stoichiometry · Carbonyl Compounds · Introduction to Organic Chemistry · Equilibria · Halogen Compounds · +7 more

Q1EquilibriaHydroxy CompoundsHalogen CompoundsFree sample

Ammonium sulfate is a fertiliser which is manufactured by the reaction between ammonia and sulfuric acid.

(a)

Ammonia is described as a weak base and sulfuric acid as a strong acid.

By using an equation, explain clearly what is meant by the term weak base.

3M
(b)

Ammonia and sulfuric acid are both manufactured by processes which involve chemical equilibria.

(i)

Sulfuric acid is produced from sulfur trioxide which is made by the Contact process.

State three important operating conditions for the Contact process for the manufacture of sulfur trioxide.

For each of your conditions, you should avoid the use of vague phrases such as 'high temperature'.

condition 1 .................................................................................................................

condition 2 .................................................................................................................

condition 3 .................................................................................................................

3M
(ii)

How is the sulfur trioxide produced converted into sulfuric acid?

1M
(c)

Chloropropanols such as 1,3-dichloropropan-2-ol (1,3-DCP) are present in some foods.

ClCH2CH(OH)CH2Cl\text{ClCH}_2\text{CH(OH)CH}_2\text{Cl}

1,3-DCP

4M
(i)

What will be produced when 1,3-DCP is reacted separately with the following reagents under suitable conditions?
In each case give the structural formula.

concentrated sulfuric acid

an excess of ammonia

(ii)

Describe as fully as you can what type of reaction occurs with ammonia.

The rest of this paper

4 more questions
  • Q2Atoms, Molecules and Stoichiometry · Electrochemistry10M
  • Q3Group 2 · Chemical Bonding · Chemical Periodicity · States of Matter15M
  • Q4Hydroxy Compounds · Hydrocarbons · Carbonyl Compounds · Introduction to Organic Chemistry · Atoms, Molecules and Stoichiometry13M
  • Q5Atoms, Molecules and Stoichiometry · Introduction to Organic Chemistry · Carboxylic Acids and Derivatives · Carbonyl Compounds · Hydroxy Compounds11M
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