5070/32

Chemistry 5070/32May/June 2025

Cambridge O-Level · Practical Test · worked solutions for every part, with the mark scheme

3
questions
40
marks
90
minutes

Topics Experimental Contexts · Observations and Measurements · Analysis, Conclusions and Evaluation · Use of Techniques, Apparatus and Materials · Qualitative Analysis · Planning Experiments and Investigations

Q117MMediumExperimental ContextsObservations and MeasurementsAnalysis, Conclusions and EvaluationUse of Techniques, Apparatus and Materials

Solid W is an impure organic acid, H3A\text{H}_3\text{A}.

You are going to determine the mass of H3A\text{H}_3\text{A} in a sample of W by titration with 0.100 mol / dm30.100\text{ mol / dm}^3 sodium hydroxide, NaOH\text{NaOH}.

You are provided with a sample of W.

Read all the instructions carefully before starting the experiments.

Instructions

(a)

Preparation of mixture X

  • Place the sample of W in a 250 cm3250\text{ cm}^3 beaker.
  • Use a measuring cylinder to add 100 cm3100\text{ cm}^3 of distilled water to the beaker.
  • Stir the mixture until the solid is fully dissolved.
  • Label this mixture X.
2M
(i)

Explain why it is important to use distilled water and not tap water for the experiment.

______

1M
(ii)

Describe the appearance of X after stirring.

______

1M
(b)

Titration of 0.100 mol / dm30.100\text{ mol / dm}^3 NaOH\text{NaOH} with X.

  • Rinse a burette with distilled water and then with X.
  • Fill the burette with X.
  • Record in Table 1.1 the initial burette reading.
  • Use a volumetric pipette to add 25.0 cm325.0\text{ cm}^3 of the 0.100 mol / dm30.100\text{ mol / dm}^3 NaOH\text{NaOH} to a conical flask.
  • Add five drops of thymolphthalein indicator to the conical flask.
  • Add X from the burette while swirling the flask, adding drop by drop near the end-point, until the solution just changes colour.
  • Record in Table 1.1 the final burette reading.
  • Repeat this titration two more times.
6M
(i)

Record in Table 1.1 the burette readings from your titrations and complete the table with the volume used in each titration.

Tick (✓) the best titration results.

Table 1.1

titration 1titration 2titration 3
final burette reading / cm3\text{cm}^3
initial burette reading / cm3\text{cm}^3
volume used / cm3\text{cm}^3
best titration results (✓)
5M
(ii)

Use the best titration results (✓) to calculate the average volume of X used.

average volume = ______ cm3\text{cm}^3

1M
(c)

Calculate the number of moles of NaOH\text{NaOH} in 25 cm325\text{ cm}^3 of 0.100 mol / dm30.100\text{ mol / dm}^3 NaOH\text{NaOH}.

number of moles = ______

1M
(d)

The equation for the reaction between H3A\text{H}_3\text{A} and NaOH\text{NaOH} is shown.

H3A+3NaOHNa3A+3H2O\text{H}_3\text{A} + 3\text{NaOH} \rightarrow \text{Na}_3\text{A} + 3\text{H}_2\text{O}

Calculate the number of moles of H3A\text{H}_3\text{A} that react with 25 cm325\text{ cm}^3 of 0.100 mol / dm30.100\text{ mol / dm}^3 NaOH\text{NaOH}.

number of moles = ______

1M
(e)

Calculate the number of moles of H3A\text{H}_3\text{A} in the sample of W.

number of moles = ______

1M
(f)

The relative molecular mass of H3A\text{H}_3\text{A} is 210.

Calculate the mass of H3A\text{H}_3\text{A} in the sample of W.

mass = ______ g\text{g}

1M
(g)

In (a) a measuring cylinder is used to add 100 cm3100\text{ cm}^3 of distilled water to the beaker.

Explain why using the measuring cylinder makes the volume of distilled water used inaccurate. Suggest an improvement.

explanation ______

improvement ______

2M
(h)

In (b) the burette is rinsed with distilled water and then with X.

3M
(i)

Explain why the burette is rinsed with distilled water.

______

1M
(ii)

Suggest and explain the effect on the titration results if the burette is not rinsed with X after rinsing with distilled water.

effect ______

explanation ______

2M
Q217MMedium-EasyQualitative AnalysisUse of Techniques, Apparatus and MaterialsObservations and MeasurementsExperimental ContextsAnalysis, Conclusions and Evaluation

You are provided with solid A and solution B.

Do the following tests on A and B.

Record your observations and conclusions for these tests.

Test and name any gases evolved.

(a)

Do a flame test on one sample of A. Describe the method you use.

method ______

observations ______

conclusion ______

4M
(b)
6M
(i)

Place the other sample of A in a test-tube and add 3 cm3\text{ cm} depth of dilute hydrochloric acid.

When the reaction has finished, keep the contents of the test-tube for use in (c).

observations ______

conclusion ______

5M
(ii)

Explain how you know when the reaction has finished.

______

1M
(c)

Decant 1 cm1\text{ cm} depth of the solution from (b)(i) into each of two test-tubes.

3M
(i)

To one of these test-tubes, add aqueous ammonia until no further change is observed.

observations ______

2M
(ii)

To the second test-tube, add aqueous sodium hydroxide until no further change is observed.

observations ______

1M
(d)

Identify solid A.

______

1M
(e)

Place 1 cm1\text{ cm} depth of aqueous silver nitrate into each of four test-tubes.

Add 1 cm1\text{ cm} depth of dilute nitric acid to each of these test-tubes.

Keep the contents of all four test-tubes until you have completed all of part (e).

To the first test-tube add 1 cm1\text{ cm} depth of aqueous sodium chloride.

To the second test-tube add 1 cm1\text{ cm} depth of aqueous potassium bromide.

To the third test-tube add 1 cm1\text{ cm} depth of aqueous potassium iodide.

To the fourth test-tube add 1 cm1\text{ cm} depth of B.

Leave the test-tubes for at least 1 minute before recording your observations in Table 2.1.

Table 2.1

solutionobservation
sodium chloride
potassium bromide
potassium iodide
B

State the conclusion about B you can make from these observations.

conclusion ______

3M
Q36MMediumPlanning Experiments and InvestigationsExperimental Contexts

You are not expected to do any experimental work for this question.

Q is a mixture of solid copper(II) carbonate and solid lead sulfate.

Lead sulfate is insoluble in water and does not react with dilute sulfuric acid.

Copper(II) carbonate is insoluble in water. It reacts with dilute sulfuric acid to form copper(II) sulfate solution.

Plan an investigation to obtain pure copper(II) sulfate crystals and pure lead sulfate solid from Q.

Your plan should describe the use of common laboratory apparatus, dilute sulfuric acid and Q. No other chemicals should be used.

Your plan should include:

  • the apparatus needed
  • the preparation of copper(II) sulfate solution
  • the method to obtain pure copper(II) sulfate crystals
  • the method to obtain pure lead sulfate solid
  • how to test that the lead sulfate is pure.

You may draw a diagram to help answer the question.

Similar questions