5070/32

Chemistry 5070/32October/November 2020

Cambridge O-Level · Practical Test · worked solutions for every part, with the mark scheme

2
questions
40
marks
90
minutes

Topics Observations and Measurements · Experimental Contexts · Analysis, Conclusions and Evaluation · Qualitative Analysis

Q117MObservations and MeasurementsExperimental ContextsAnalysis, Conclusions and EvaluationFree sample

A weak acid has the formula H3X\text{H}_3\text{X}.

The equation for the reaction between H3X\text{H}_3\text{X} and sodium hydroxide, NaOH\text{NaOH}, is shown.

3NaOH+H3XNa3X+3H2O3\text{NaOH} + \text{H}_3\text{X} \rightarrow \text{Na}_3\text{X} + 3\text{H}_2\text{O}

The concentration of H3X(aq)\text{H}_3\text{X(aq)} is determined by titration with NaOH(aq)\text{NaOH(aq)}.

Thymolphthalein is used to determine the end-point of the titration.

P is H3X(aq)\text{H}_3\text{X(aq)}.

Q is 0.100 mol / dm3 NaOH(aq)0.100\text{ mol / dm}^3\text{ NaOH(aq)}.

(a)

Put P into the burette.

Pipette 25.0 cm325.0\text{ cm}^3 of Q into a flask and titrate with P using three drops of thymolphthalein as the indicator.

The end-point is when the solution remains colourless for 30 seconds.

Record your results in the table.

Repeat the titration as many times as necessary to achieve consistent results.

Results

Burette readings

titration number12
final reading / cm3\text{cm}^3
initial reading / cm3\text{cm}^3
volume of P used / cm3\text{cm}^3
best titration results (✓)

Summary

Tick (✓) the best titration results in the table.

Using the best titration results the average volume of P required is ______ cm3\text{cm}^3.

12M
(b)

Q is 0.100 mol / dm3 NaOH(aq)0.100\text{ mol / dm}^3\text{ NaOH(aq)}.

Calculate the number of moles of NaOH\text{NaOH} in 25.0 cm325.0\text{ cm}^3 of Q.

Give your answer to three significant figures.

number of moles of NaOH\text{NaOH} in 25 cm325\text{ cm}^3 of Q = ______

1M
(c)

Use your answer from (b) to calculate the number of moles of H3X\text{H}_3\text{X} in the average volume of P used.

3NaOH+H3XNa3X+3H2O3\text{NaOH} + \text{H}_3\text{X} \rightarrow \text{Na}_3\text{X} + 3\text{H}_2\text{O}

number of moles of H3X\text{H}_3\text{X} = ______

1M
(d)

Use your answers from (a) and (c) to calculate the concentration of H3X(aq)\text{H}_3\text{X(aq)} in P in mol / dm3\text{mol / dm}^3.

concentration of H3X(aq)\text{H}_3\text{X(aq)} = ______ mol / dm3\text{mol / dm}^3

1M
(e)

Use your answer from (d) to calculate the mass of H3X\text{H}_3\text{X} in 200 cm3 P200\text{ cm}^3\text{ P}.

[MrM_r: H3X\text{H}_3\text{X}, 192]

mass of H3X\text{H}_3\text{X} = ______ g\text{g}

2M

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