5070/22

Chemistry 5070/22October/November 2019

Cambridge O-Level · Theory · worked solutions for every part, with the mark scheme

9
questions
75
marks
90
minutes

Topics Stoichiometry · Acids, Bases and Salts · The Periodic Table · Experimental Techniques and Chemical Analysis · Metals · Organic Chemistry · +6 more

Q15MThe Periodic TableExperimental Techniques and Chemical AnalysisMetalsChemistry of the EnvironmentFree sample

The diagram shows part of the Periodic Table.

Answer the questions using only the elements shown in the diagram.

Each element may be used once, more than once or not at all.

Write the symbol for an element which:

(a)

forms a stable ion of type X2\text{X}^{2-}

______

1M
DifficultyEasy
Worked solution

Answer

O (or S or Se)

Final answer

O

Detailed explanation

Walkthrough

Elements in Group VI (Group 16) of the Periodic Table have six electrons in their outer shell. To achieve a stable octet, they gain two electrons to form a stable ion with a 2- charge (X^{2-}). Looking at the provided diagram, the Group VI elements are oxygen (O), sulphur (S), and selenium (Se). Any of these symbols is a correct answer.

Key Takeaways

The group number in the Periodic Table determines the charge of the simple ion formed by non-metals. Group VI elements gain two electrons to form X^{2-} ions.

Common Mistakes

  • Writing the name of the element (e.g., "oxygen") instead of the chemical symbol ("O"). The question explicitly asks for the symbol.
  • Suggesting an element from Group V (forms 3-) or Group VII (forms 1-).

Things to Be Careful About

The question asks for "the symbol", not the name. Any of O, S, or Se is acceptable. Ensure the symbol is written correctly (capital first letter, lowercase second if applicable, though all three here are single letters).

Techniques used
deduce ionic charge from group numberidentify Group VI elements from the diagram
(b)

is a light green gas at room temperature

______

1M
DifficultyEasy
Worked solution

Answer

Cl

Final answer

Cl

Detailed explanation

Walkthrough

The halogens in Group VII have distinct physical properties at room temperature that change down the group. Fluorine (F) is a pale yellow gas, chlorine (Cl) is a light green gas, bromine (Br) is a reddish-brown liquid, and iodine (I) is a dark grey-black solid. From the elements shown in the diagram, chlorine (Cl) is the only light green gas.

Key Takeaways

The physical states and colours of the halogens change down the group: F (pale yellow gas), Cl (green gas), Br (red-brown liquid), I (grey-black solid). Melting and boiling points increase down the group.

Common Mistakes

  • Confusing chlorine with fluorine (which is a pale yellow gas) or bromine (which is a reddish-brown liquid).
  • Writing the name "chlorine" instead of the symbol "Cl".

Things to Be Careful About

The question asks for the symbol. Chlorine is a diatomic gas (Cl_2), but the question asks for the symbol of the element, which is Cl.

Techniques used
recall physical properties of halogens
(c)

forms an ion which gives a yellow precipitate on addition of aqueous silver nitrate

______

1M
DifficultyEasy
Worked solution

Answer

I

Final answer

I

Detailed explanation

Walkthrough

When aqueous silver nitrate (acidified with dilute nitric acid) is added to a solution containing halide ions, a precipitate of silver halide forms. The colour of the precipitate identifies the halide ion: chloride (Cl^-) gives a white precipitate, bromide (Br^-) gives a cream precipitate, and iodide (I^-) gives a yellow precipitate. The yellow precipitate is silver iodide (AgI). Therefore, the element that forms the iodide ion is iodine, symbol I.

Key Takeaways

The silver nitrate test distinguishes halide ions by the colour of the precipitate: Cl^- (white), Br^- (cream), I^- (yellow). The test must be carried out in the presence of dilute nitric acid to remove interfering ions like carbonate.

Common Mistakes

  • Confusing the colours of the precipitates (e.g., thinking bromide gives a yellow precipitate).
  • Writing the name "iodine" instead of the symbol "I".
  • Forgetting that the test is for the ion, so the element must be one that forms that ion (iodine forms I^-).

Things to Be Careful About

The mark scheme accepts only the symbol "I". The precipitate is silver iodide, not silver chloride or silver bromide. Ensure the symbol is written with a capital I.

Techniques used
identify halide ion from silver nitrate test
(d)

is used to make food containers

______

1M
DifficultyEasy
Worked solution

Answer

Al

Final answer

Al

Detailed explanation

Walkthrough

Aluminium is widely used to make food containers, such as cans and foil, because it is lightweight (low density), does not react with food (it forms a tough, protective oxide layer on its surface), and is a good conductor of heat. From the elements shown in the diagram, aluminium is Al.

Key Takeaways

Aluminium's low density, resistance to corrosion (due to its protective oxide layer), and malleability make it ideal for food packaging, containers, and foil.

Common Mistakes

  • Suggesting iron or copper for food containers (iron rusts and copper can react with acidic foods).
  • Writing the name "aluminium" instead of the symbol "Al".

Things to Be Careful About

The question asks for the symbol. Must provide "Al" with the correct capitalisation (capital A, lowercase l).

Techniques used
recall common uses of metals
(e)

is a diatomic gas which forms 78% of dry air.

______

1M
DifficultyEasy
Worked solution

Answer

N

Final answer

N

Detailed explanation

Walkthrough

Clean, dry air is composed mainly of nitrogen (about 78%) and oxygen (about 21%), with small amounts of argon (about 0.9%) and carbon dioxide (about 0.04%). Nitrogen is a diatomic gas (N_2). From the elements shown in the diagram, nitrogen is N.

Key Takeaways

The composition of clean, dry air is approximately 78% nitrogen, 21% oxygen, and 1% other gases (mostly argon). Nitrogen is a diatomic, unreactive gas.

Common Mistakes

  • Confusing nitrogen with oxygen (which is about 21% and supports combustion).
  • Writing the name "nitrogen" instead of the symbol "N".
  • Suggesting argon (which is monatomic, not diatomic, and makes up about 1% of air).

Things to Be Careful About

The question asks for the symbol and specifies "diatomic gas", which rules out argon (monatomic). Must provide "N" with a capital letter.

Techniques used
recall composition of dry air

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