5070/31

Chemistry 5070/31October/November 2018

Cambridge O-Level · Practical Test · worked solutions for every part, with the mark scheme

2
questions
40
marks
90
minutes

Topics Experimental Contexts · Observations and Measurements · Analysis, Conclusions and Evaluation · Qualitative Analysis

Q118MExperimental ContextsObservations and MeasurementsAnalysis, Conclusions and EvaluationFree sample

When solid sodium hydroxide is exposed to the air, it absorbs water. As a result, the solid becomes damp.

P is a solution containing 9.82 g / dm39.82\text{ g / dm}^3 of a sample of damp sodium hydroxide.

Q is 0.105 mol / dm30.105\text{ mol / dm}^3 sulfuric acid.

You are to determine the amount of water in the sample by titrating the sodium hydroxide in P with Q.

2NaOH+H2SO4Na2SO4+2H2O2\text{NaOH} + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + 2\text{H}_2\text{O}
(a)

Put Q into the burette.

Pipette a 25.0 cm325.0\text{ cm}^3 (or 20.0 cm320.0\text{ cm}^3) portion of P into a flask and titrate with Q, using the indicator provided.

Record your results in the table, repeating the titration as many times as you consider necessary to achieve consistent results.

Results

Burette readings

titration number12
final reading / cm3\text{cm}^3
initial reading / cm3\text{cm}^3
volume of Q used / cm3\text{cm}^3
best titration results (✓)

Summary

Tick (✓) the best titration results.

Using the best titration results, the average volume of Q required was ______ cm3\text{cm}^3.

Volume of solution P used was ______ cm3\text{cm}^3.

12M
(b)

Q is 0.105 mol / dm30.105\text{ mol / dm}^3 sulfuric acid.

Calculate the number of moles of sulfuric acid present in the average volume of Q.

moles of sulfuric acid in the average volume of Q = ______

1M
(c)

Using your answer from (b) and the equation shown, calculate the number of moles of sodium hydroxide in the volume of P used in the titration.

2NaOH+H2SO4Na2SO4+2H2O2\text{NaOH} + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + 2\text{H}_2\text{O}

moles of sodium hydroxide in the volume of P used = ______

1M
(d)

Using your answer from (c), calculate the concentration, in mol / dm3\text{mol / dm}^3, of sodium hydroxide in P.

concentration of sodium hydroxide in P = ______ mol / dm3\text{mol / dm}^3

1M
(e)

Using your answer from (d), calculate the mass, in g, of sodium hydroxide in 1.00 dm31.00\text{ dm}^3 of P.
[MrM_r: NaOH, 40]

mass of sodium hydroxide in 1.00 dm31.00\text{ dm}^3 of P = ______ g\text{g}

1M
(f)

Using your answer from (e), calculate the mass of water present in the 9.82 g9.82\text{ g} of damp sodium hydroxide used to make P.

mass of water present in 9.82 g9.82\text{ g} of damp sodium hydroxide = ______ g\text{g}

1M
(g)

Calculate the percentage by mass of water present in the damp sodium hydroxide used to make P.

percentage by mass of water = ______

1M

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